Issue 21, 2014
From the journal:

Polymer Chemistry

Network formation mechanisms in conjugated microporous polymers†

Andrea Laybourn,a   Robert Dawson,ab   Rob Clowes,a   Tom Hasell,a   Andrew I. Cooper,a   Yaroslav Z. Khimyakc  and  Dave J. Adams*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: d.j.adams@liverpool.ac.uk

b Institute of Chemistry, Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, Berlin, Germany

c School of Pharmacy, University of East Anglia, Norwich Research Park, Norwich, UK

Abstract

We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

Graphical abstract: Network formation mechanisms in conjugated microporous polymers

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Article information

DOI
https://doi.org/10.1039/C4PY00647J
Article type
Paper
Submitted
08 May 2014
Accepted
20 Jul 2014
First published
21 Jul 2014
This article is Open Access
Creative Commons BY license

Polym. Chem., 2014,5, 6325-6333

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Network formation mechanisms in conjugated microporous polymers

A. Laybourn, R. Dawson, R. Clowes, T. Hasell, A. I. Cooper, Y. Z. Khimyak and D. J. Adams, Polym. Chem., 2014, 5, 6325 DOI: 10.1039/C4PY00647J

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