Issue 30, 2015
From the journal:

Dalton Transactions

Field and dilution effects on the magnetic relaxation behaviours of a 1D dysprosium(iii)-carboxylate chain built from chiral ligands†

Tian Han,a   Ji-Dong Leng,a   You-Song Ding,a   Yanyan Wang,a   Zhiping Zhengab  and  Yan-Zhen Zheng*a  

* Corresponding authors

a Center for Applied Chemical Research, Frontier Institute of Science and Technology, and College of Science, Xi'an Jiaotong University, Xi'an 710054, China
E-mail: zheng.yanzhen@mail.xjtu.edu.cn

b Department of Chemistry, The University of Arizona, Tucson, Arizona 85721, USA

Abstract

A one-dimensional dysprosium(III)-carboxylate chain in which the DyIII ions sit in a pseudo D2d-symmetry environment is synthesized and shows different slow magnetic relaxation behaviours depending on the field and dilution effects. Besides, the chiral ligand introduces the additional functions of the Cotton effect and polarization for this compound.

Graphical abstract: Field and dilution effects on the magnetic relaxation behaviours of a 1D dysprosium(iii)-carboxylate chain built from chiral ligands

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Article information

DOI
https://doi.org/10.1039/C4DT03980G
Article type
Communication
Submitted
24 Dec 2014
Accepted
25 Jun 2015
First published
10 Jul 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 13480-13484

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Field and dilution effects on the magnetic relaxation behaviours of a 1D dysprosium(III)-carboxylate chain built from chiral ligands

T. Han, J. Leng, Y. Ding, Y. Wang, Z. Zheng and Y. Zheng, Dalton Trans., 2015, 44, 13480 DOI: 10.1039/C4DT03980G

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