Issue 80, 2014

Porous organic ligands (POLs) for synthesizing highly efficient heterogeneous catalysts

Abstract

We reported a universal route for synthesizing porous organic ligands (POLs) via solvothermal polymerization. The POLs were obtained quantitatively, showing high surface area, large pore volume, hierarchical porosity, and superior stability. The POL bearing a triphenylphosphine supported rhodium catalyst (Rh/POL-PPh3) exhibits high activity and excellent recyclability in 1-octene hydroformylation.

Graphical abstract: Porous organic ligands (POLs) for synthesizing highly efficient heterogeneous catalysts

Supplementary files

Article information

Article type
Communication
Submitted
21 May 2014
Accepted
09 Aug 2014
First published
14 Aug 2014

Chem. Commun., 2014,50, 11844-11847

Porous organic ligands (POLs) for synthesizing highly efficient heterogeneous catalysts

Q. Sun, M. Jiang, Z. Shen, Y. Jin, S. Pan, L. Wang, X. Meng, W. Chen, Y. Ding, J. Li and F. Xiao, Chem. Commun., 2014, 50, 11844 DOI: 10.1039/C4CC03884C

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