Issue 18, 2013

Cleavage of the C–S bond with the formation of a binuclear copper complex with 2-thiolato-3-phenyl-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazole-4-one. A new mimic of the active site of N2O reductase

Abstract

The treatment of the ligands with copper(II) chloride dihydrate led to the formation of a binuclear copper complex with a [Cu+1.5Cu+1.5] redox state as a result of C–S bond cleavage in the course of the reaction. This complex catalyses the electrochemical reduction of nitrous oxide and triphenyl phosphine oxidation under N2O action.

Graphical abstract: Cleavage of the C–S bond with the formation of a binuclear copper complex with 2-thiolato-3-phenyl-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazole-4-one. A new mimic of the active site of N2O reductase

Supplementary files

Article information

Article type
Communication
Submitted
14 Feb 2013
Accepted
04 Mar 2013
First published
04 Mar 2013

Dalton Trans., 2013,42, 6290-6293

Cleavage of the C–S bond with the formation of a binuclear copper complex with 2-thiolato-3-phenyl-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazole-4-one. A new mimic of the active site of N2O reductase

A. G. Majouga, E. K. Beloglazkina, A. A. Moiseeva, O. V. Shilova, E. A. Manzheliy, M. A. Lebedeva, E. S. Davies, A. N. Khlobystov and N. V. Zyk, Dalton Trans., 2013, 42, 6290 DOI: 10.1039/C3DT50422K

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