Issue 54, 2014
From the journal:

Chemical Communications

A single chain magnet involving hexacyanoosmate†

Eugenia V. Peresypkina,a   Anna M. Majcher,b   Michał Rams*b  and  Kira E. Vostrikova‡*a  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry, 3 Acad. Lavrentiev avenue, Novosibirsk, Russia
E-mail: vosk@niic.nsc.ru

b Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków, Poland
E-mail: m.rams@uj.edu.pl

Abstract

The first single chain magnet (SCM) based on orbitally degenerate hexacyanoosmate(III) was prepared. The high values of energy barriers for the [Mn(acacen)Os(CN)6]2− complex of 81 and 48.4 K are the result of interplay of three axes anisotropic coupling of [Os(CN)6]3− with zero field splitted Mn3+.

Graphical abstract: A single chain magnet involving hexacyanoosmate

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC48972H
Article type
Communication
Submitted
25 Nov 2013
Accepted
12 May 2014
First published
12 May 2014

Chem. Commun., 2014,50, 7150-7153

Author version available

Download author version (PDF)

Permissions

Request permissions

A single chain magnet involving hexacyanoosmate

E. V. Peresypkina, A. M. Majcher, M. Rams and K. E. Vostrikova, Chem. Commun., 2014, 50, 7150 DOI: 10.1039/C3CC48972H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements