Issue 56, 2013

Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: structural insights and solvent effects

Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

Graphical abstract: Abrupt spin crossover in an iron(iii) quinolylsalicylaldimine complex: structural insights and solvent effects

Supplementary files

Article information

Article type
Communication
Submitted
24 Mar 2013
Accepted
04 Jun 2013
First published
04 Jun 2013

Chem. Commun., 2013,49, 6340-6342

Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

D. J. Harding, W. Phonsri, P. Harding, I. A. Gass, K. S. Murray, B. Moubaraki, J. D. Cashion, L. Liu and S. G. Telfer, Chem. Commun., 2013, 49, 6340 DOI: 10.1039/C3CC42125B

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