Issue 2, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

A novel, highly copper(II)-selective chelating hydrophilic ion exchanger based on imidazole modified poly(glycidyl methacrylate)

Petronella M. van Berkel,   Willem L. Driessen,   G. J. Anthony,   A. Kodhaas,   Jan Reedijk  and  David C. Sherrington  

Abstract

Anchoring the imidazole ligand bis(imidazo-2-yl)methylaminomethane (bimam) onto poly(glycidyl methacrylate-co-trimethylpropane trimethacrylate)(pGMT) by a ring-opening reaction of the pendant epoxy group with the secondary amine group of the ligand, results in a novel hydrophilic resin, which contains 0.59 mmol of the ligand per gram of resin; the ligand binding and the resin structure have been characterized by 13C solid-state CP-MAS NMR spectroscopy and elemental analyses; batch extraction experiments show a very high selectivity in the pH range 1.1–6.0 for Cu2+ over Ni2+, Co2+, Zn2+ and Cd2+, as chloride salts in buffered solutions under competitive conditions.

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Article information

DOI
https://doi.org/10.1039/C39950000147
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 147-148

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A novel, highly copper(II)-selective chelating hydrophilic ion exchanger based on imidazole modified poly(glycidyl methacrylate)

P. M. van Berkel, W. L. Driessen, G. J. Anthony, A. Kodhaas, J. Reedijk and D. C. Sherrington, J. Chem. Soc., Chem. Commun., 1995, 147 DOI: 10.1039/C39950000147

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