The oxidation of primary aromatic amines to the corresponding nitro derivatives has been observed in catalytic systems (turnovers/hour up to 18000) containing tert-butyl hydroperoxide and metallo-tetraaryl porphyrins (metal = FeIII or MnIII) in the presence of heterocyclic nitrogen bases acting as axial ligands.
S. Tollari, D. Vergani, S. Banfi and F. Porta, J. Chem. Soc., Chem. Commun., 1993, 442 DOI: 10.1039/C39930000442
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