Issue 14, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

The preparation, X-ray crystal structure and theoretical study of [CoCp2][S3N3], (Cp = cyclopentadienyl), a novel stacking compound incorporating multiple C–H ⋯ N(pπ) interactions

Philip N. Jagg,   Paul F. Kelly,   Henry S. Rzepa,   David J. Williams,   J. Derek Woollins  and  William Wylie  

Abstract

Reaction of cobaltocene, [CoCp2], with S4N4 in tetrahydrofuran (thf) results in precipitation of the cobaltocenium salt [CoCp2][S3N3]1 in good yield; the X-ray crystal structure together with theoretical calculations reveal an accumulation of unique C–H ⋯ N ⋯ H–C (pπ) interactions that result in the formation of continuous stacks of alternating cations and anions.

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Article information

DOI
https://doi.org/10.1039/C39910000942
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 942-944

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The preparation, X-ray crystal structure and theoretical study of [CoCp2][S3N3], (Cp = cyclopentadienyl), a novel stacking compound incorporating multiple C–H ⋯ N(pπ) interactions

P. N. Jagg, P. F. Kelly, H. S. Rzepa, D. J. Williams, J. D. Woollins and W. Wylie, J. Chem. Soc., Chem. Commun., 1991, 942 DOI: 10.1039/C39910000942

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