Issue 11, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Defining the stoicheiometry of a subcarbonylmetal guest using mixed vibrational isotope labelling techniques

Geoffrey A. Ozin,   Saim Özkar  and  Douglas F. McIntosh  

Abstract

The tricarbonyl stoicheiometry, structure, and anchoring site geometry of M(CO)3–M*56Y which are cleanly generated via the mild vacuum thermal decarbonylation of M(CO)6–M*56Y (where M = Cr, Mo, or W; M*= Li, Na, K, Rb, or Cs; Y = dehydrated zeolite Y), have been unequivocally established for the first time from analysis of their M(12CO)n(13CO)3-n–M*56Y vibrational isotope patterns.

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Article information

DOI
https://doi.org/10.1039/C39900000841
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 841-843

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Defining the stoicheiometry of a subcarbonylmetal guest using mixed vibrational isotope labelling techniques

G. A. Ozin, S. Özkar and D. F. McIntosh, J. Chem. Soc., Chem. Commun., 1990, 841 DOI: 10.1039/C39900000841

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