Issue 18, 1986

A novel type of tetranuclear copper(II) cluster, containing deprotonated 3-(pyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazole (Hppt) as a diatomic bridging ligand. Preparation, magnetism, and X-ray crystal structure of [Cu(µ-ppt)(H2O)]4(NO3)4(H2O)12

Abstract

The title compound, characterized by means of an X-ray structure analysis, represents the first example of a tetranuclear co-ordination compound with only diatomic bridges.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1430-1431

A novel type of tetranuclear copper(II) cluster, containing deprotonated 3-(pyridin-2-yl)-5-(pyrazin-2-yl)-1,2,4-triazole (Hppt) as a diatomic bridging ligand. Preparation, magnetism, and X-ray crystal structure of [Cu(µ-ppt)(H2O)]4(NO3)4(H2O)12

R. Prins, R. A. G. de Graaff, J. G. Haasnoot, C. Vader and J. Reedijk, J. Chem. Soc., Chem. Commun., 1986, 1430 DOI: 10.1039/C39860001430

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