Issue 20, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Chiral discrimination in the reaction of the enolate [(η5-C5H5)Fe(CO)(PPh3)(COCH2)]–Li+ with monosubstituted epoxides: X-ray crystal structure of (RS,SR)-[(η5-C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}]

Stephen L. Brown,   Stephen G. Davies,   Peter Warner,   Richard H. Jones  and  Keith Prout  

Abstract

In the presence of Et2AICI, the lithium enolate derived form the iron acetyl complex [(η5-C5H5)Fe(CO)(PPh3)(COMe)] discriminates between the enantiomers of monosubstituted epoxides to produce essentially only one product diastereoisomer, for example(RS,SR)-[(η5C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}] in the case of propene oxide.

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Article information

DOI
https://doi.org/10.1039/C39850001446
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1446-1447

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Chiral discrimination in the reaction of the enolate [(η5-C5H5)Fe(CO)(PPh3)(COCH2)]–Li+ with monosubstituted epoxides: X-ray crystal structure of (RS,SR)-[(η5-C5H5)Fe(CO)(PPh3){COCH2CH2CH(OH)Me}]

S. L. Brown, S. G. Davies, P. Warner, R. H. Jones and K. Prout, J. Chem. Soc., Chem. Commun., 1985, 1446 DOI: 10.1039/C39850001446

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