A new imidazole-containing octadentate ligand, capable of binding two metal ions; the X-ray structure of the dinuclear ZnCl2 adduct of 1,1,4,7,7-penta(benzimidazol-2-ylmethyl)-1,4,7-triazaheptane

Paul J. M. W. L. Birker; Abraham J. Schierbeek; Gerrit C. Verschoor; Jan Reedijk

doi:10.1039/C39810001124

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A new imidazole-containing octadentate ligand, capable of binding two metal ions; the X-ray structure of the dinuclear ZnCl₂ adduct of 1,1,4,7,7-penta(benzimidazol-2-ylmethyl)-1,4,7-triazaheptane

Paul J. M. W. L. Birker, Abraham J. Schierbeek, Gerrit C. Verschoor and Jan Reedijk

Abstract

Dinuclear Cu^II and Zn^II compounds of the new ligand 1, 1, 4, 7, 7-penta(benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane were synthesized; the X-ray structure of the Zn compound shows that one Zn atom is six-co-ordinated by one Cl and five N atoms, whereas the second Zn atom is five-co-ordinated by three N and two Cl atoms.

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DOI: https://doi.org/10.1039/C39810001124
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1981, 1124-1125

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A new imidazole-containing octadentate ligand, capable of binding two metal ions; the X-ray structure of the dinuclear ZnCl₂ adduct of 1,1,4,7,7-penta(benzimidazol-2-ylmethyl)-1,4,7-triazaheptane

P. J. M. W. L. Birker, A. J. Schierbeek, G. C. Verschoor and J. Reedijk, J. Chem. Soc., Chem. Commun., 1981, 1124 DOI: 10.1039/C39810001124

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Journal of the Chemical Society, Chemical Communications

A new imidazole-containing octadentate ligand, capable of binding two metal ions; the X-ray structure of the dinuclear ZnCl₂ adduct of 1,1,4,7,7-penta(benzimidazol-2-ylmethyl)-1,4,7-triazaheptane

Abstract

Article information

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A new imidazole-containing octadentate ligand, capable of binding two metal ions; the X-ray structure of the dinuclear ZnCl₂ adduct of 1,1,4,7,7-penta(benzimidazol-2-ylmethyl)-1,4,7-triazaheptane

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