SCHEDULED MAINTENANCE
The reaction of three isomeric pentenols with methyl magnesium bromide catalysed by (–) DIOP nickel dicloride [DIOP =O,O′-iospropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane] leads to optically active 3-methylpent-1-ene, with the optical yield and product configuration related to the configuration of the initially formed (η3-allyl)nickel intermediates.
M. Chérest, H. Felkin, J. D. Umpleby and S. G. Davies, J. Chem. Soc., Chem. Commun., 1981, 681 DOI: 10.1039/C39810000681
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