Issue 20, 1975

Effects of metal ions on rates of detritiation–new probe in the study of metal–substrate interactions

Abstract

The rate retarding effect of metal ions (Cu2+ > Zn2+≃ Ni2+ > > MeHg+) on isotopic hydrogen exchange from the C(2) position of imidazole can be rationalised in terms of complex formation; the stability constants can be evaluated from the exchange rate constants.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 856-856

Effects of metal ions on rates of detritiation–new probe in the study of metal–substrate interactions

D. H. Buisson, J. R. Jones and S. E. Taylor, J. Chem. Soc., Chem. Commun., 1975, 856 DOI: 10.1039/C39750000856

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