Issue 14, 1972
From the journal:

Journal of the Chemical Society, Chemical Communications

Perfluoro-2,5-diazahexane-2,5-dioxyl and its use in polymer chemistry and in polymer cross-linking

R. E. Banks,   K. C. Eapen,   R. N. Haszeldine,   P. Mitra,   T. Myerscough  and  S. Smith  

Abstract

Perfluoro-2,5-diazahexane-2,5-dioxyl has been synthesised; it reacts with nitric oxide to give CF3·N(O·NO)·CF2·CF2·N(O·NO)·CF3, with hydrogen bromide, toluene, triphenylmethane, or hydrogen–Pd–BaSo4 to give CF3·N(OH)·CF2·CF2·N(OH)·CF3, and with perfluorinated olefins or dienes to give nitroso-rubbers and heterocycles, the latter type of reaction finding application in the cross-linking of trifluoronitrosomethane–tetrafluoroethylene–hexafluorobutadiene terpolymers.

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Article information

DOI
https://doi.org/10.1039/C39720000833
Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 833-834

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Perfluoro-2,5-diazahexane-2,5-dioxyl and its use in polymer chemistry and in polymer cross-linking

R. E. Banks, K. C. Eapen, R. N. Haszeldine, P. Mitra, T. Myerscough and S. Smith, J. Chem. Soc., Chem. Commun., 1972, 833 DOI: 10.1039/C39720000833

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