SCHEDULED MAINTENANCE
Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker†‡
Abstract
A two-dimensional coordination network, 2∞[FeIII (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(III)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.
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