Issue 5, 2013
From the journal:

CrystEngComm

3d–4f Heterometallic coordination polymers constructed by tetranuclear lanthanide-based cluster as secondary building unit†

Guo Peng,a   Li Ma,a   Li Liang,a   Yingzhao Ma,a   Chengfeng Yanga  and  Hong Deng*a  

* Corresponding authors

a School of Chemistry & Environment, South China Normal University; Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou 510006, P. R. China
E-mail: dh@scnu.edu.cn

Abstract

Four novel 3d–4f heterometallic coordination polymers [Dy4Mn(PDA)6(SO4)2 (H2O)4]·13H2O (1) and [Ln4M(PDA)4(SO4)2(INA)2(H2O)8]·5H2O [Ln = Gd, M = Mn (2); Ln = Eu, M = Zn (3); Ln = Tb, M = Zn (4); PDA = pyridine-2,6-dicarboxylate; INA = isonicotinate] have been hydrothermally synthesized and structurally characterized. Compound 1 possesses a 1D chainlike structure with the tetranuclear [Dy4(PDA)6(SO4)2(H2O)2] “metalloligand” linking the adjacent Mn atoms. Compounds 2–4 are isostructural and possess a 2D heterometallic layer network with a (4,4) connected topology. Furthermore, the magnetic and luminescent properties of compounds 1–4 were investigated.

Graphical abstract: 3d–4f Heterometallic coordination polymers constructed by tetranuclear lanthanide-based cluster as secondary building unit

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Article information

DOI
https://doi.org/10.1039/C2CE26277K
Article type
Paper
Submitted
10 Aug 2012
Accepted
12 Nov 2012
First published
13 Nov 2012

CrystEngComm, 2013,15, 922-930

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3d–4f Heterometallic coordination polymers constructed by tetranuclear lanthanide-based cluster as secondary building unit

G. Peng, L. Ma, L. Liang, Y. Ma, C. Yang and H. Deng, CrystEngComm, 2013, 15, 922 DOI: 10.1039/C2CE26277K

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