Issue 80, 2012
From the journal:

Chemical Communications

A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis†‡

Jinhee Park,a   Jian-Rong Li,a   Ying-Pin Chen,a   Jiamei Yu,b   Andrey A. Yakovenko,a   Zhiyong U. Wang,a   Lin-Bing Sun,a   Perla B. Balbuenab  and  Hong-Cai Zhou*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, USA
E-mail: zhou@chem.tamu.edu
Fax: +1 979-845-1595

b Artie McFerrin Department of Chemical Engineering, Texas A&M University, College Station, USA

Abstract

A multi-functional MOF PCN-124 was constructed from Cu paddlewheel motifs and a judiciously designed novel ligand bearing carboxylate, pyridine, and amide groups. PCN-124 exhibits selective adsorption of CO2 over CH4 and excellent catalytic activity in a tandem one-pot deacetalization–Knoevenagel condensation reaction as a cooperative catalyst.

Graphical abstract: A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis

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Article information

DOI
https://doi.org/10.1039/C2CC34622B
Article type
Communication
Submitted
28 Jun 2012
Accepted
21 Aug 2012
First published
22 Aug 2012

Chem. Commun., 2012,48, 9995-9997

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A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis

J. Park, J. Li, Y. Chen, J. Yu, A. A. Yakovenko, Z. U. Wang, L. Sun, P. B. Balbuena and H. Zhou, Chem. Commun., 2012, 48, 9995 DOI: 10.1039/C2CC34622B

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