Issue 49, 2012
From the journal:

Chemical Communications

Copper based metal–organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host–guest molecular system†

Zhiyong Fu,*a   Yu Zeng,a   Xiaoling Liu,a   Desheng Song,a   Shijun Liaoa  and  Jingcao Daib  

* Corresponding authors

a Key Laboratory for Fuel Cell Technology of Guangdong Province, Guangdong, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China
E-mail: zyfu@scut.edu.cn
Fax: (+86) 20 8711-2965

b Institute of Materials Physical Chemistry, Huaqiao University, Fujian, Quanzhou, China
E-mail: jcdai@hqu.edu.cn
Fax: (+86) 595 2269-0569

Abstract

Keggin polyphosphotungstate cluster was captured by a porous molecular ring with light sensitizing TPT molecules as connectors and copper ions as nodes. The self-assembly reaction gives a stable host–guest supramolecular system, demonstrating efficient heterogeneous photocatalytic behavior for the degradation of methyl orange in near-neutral conditions.

Graphical abstract: Copper based metal–organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host–guest molecular system

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Article information

DOI
https://doi.org/10.1039/C2CC32019C
Article type
Communication
Submitted
20 Mar 2012
Accepted
27 Apr 2012
First published
30 Apr 2012

Chem. Commun., 2012,48, 6154-6156

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Copper based metal–organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host–guest molecular system

Z. Fu, Y. Zeng, X. Liu, D. Song, S. Liao and J. Dai, Chem. Commun., 2012, 48, 6154 DOI: 10.1039/C2CC32019C

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