Volume 154, 2012

High pressure studies of the transport properties of ionic liquids

Abstract

High pressure measurements have been made of viscosities, ion self-diffusion coefficients and electrical conductivities of ionic liquids, mainly of imidazolium salts. We review how these properties have been analysed in terms of the empirical Stokes–Einstein, Walden and Nernst–Einstein equations, and examine trends revealed by the phenomenological approach of velocity correlation coefficients and the more general theory of density scaling. Finally we examine the possibility of dynamic crossover in the transport properties of ionic liquids.

Article information

Article type
Paper
Submitted
29 Apr 2011
Accepted
31 May 2011
First published
13 Jul 2011

Faraday Discuss., 2012,154, 425-438

High pressure studies of the transport properties of ionic liquids

K. R. Harris and M. Kanakubo, Faraday Discuss., 2012, 154, 425 DOI: 10.1039/C1FD00085C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements