Issue 3, 2012
From the journal:

Dalton Transactions

Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands†

John F. Becka  and  Joseph A. R. Schmidt*a  

* Corresponding authors

a Department of Chemistry, School for Green Chemistry and Engineering, College of Natural Sciences & Mathematics, The University of Toledo, 2801 W. Bancroft St. MS 602, Toledo, USA

Abstract

Several late transition metal and main grouporthometallated imine complexes were synthesized by utilizing ortholithiated imine precursors. Magnesium, aluminum, zinc, copper(I), and tin(IV) complexes were isolated and characterized. Subsequent reactions with electrophiles such as Ph2PCl, MeI and I2 yielded several functionalized products, including a new iminophosphine ligand and its corresponding copper(I) complex. The coordination modes of the orthometallated imine ligands, as well as the structures of the metal complexes, were studied in the solid state using small molecule X-ray diffraction when possible.

Graphical abstract: Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands

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Article information

DOI
https://doi.org/10.1039/C1DT11629K
Article type
Paper
Submitted
29 Aug 2011
Accepted
08 Oct 2011
First published
17 Nov 2011

Dalton Trans., 2012,41, 860-870

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Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands

J. F. Beck and J. A. R. Schmidt, Dalton Trans., 2012, 41, 860 DOI: 10.1039/C1DT11629K

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