Issue 32, 2011
From the journal:

Dalton Transactions

A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworks†

Xiang Zhao,a   Tao Wu,a   Xianhui Bub  and  Pingyun Feng*a  

* Corresponding authors

a Department of Chemistry, University of California, Riverside, CA, USA
E-mail: pingyun.feng@ucr.edu
Fax: (+1) 951-827-4713
Tel: (+1) 951-827-2042

b Department of Chemistry and Biochemistry, California State University, 1250 Bellflower Blvd., Long Beach, CA, USA
Fax: (+1) 562-985-8557
Tel: (+1) 562-985-4843

Abstract

Reported here are two 4-connected 3D frameworks based on monomeric lithium nodes, which are synthesized through a mixed ligand route. By combining a negatively charged imidazole ligand and a neutral bis(imidazolyl)methane ligand (or one of its derivatives), neutral frameworks adopting chiral quartz-dual and diamond topologies have been obtained. These materials have low framework density and can reversibly adsorb hydrogen gas.

Graphical abstract: A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworks

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Article information

DOI
https://doi.org/10.1039/C1DT10859J
Article type
Communication
Submitted
07 May 2011
Accepted
18 Jun 2011
First published
15 Jul 2011

Dalton Trans., 2011,40, 8072-8074

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A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworks

X. Zhao, T. Wu, X. Bu and P. Feng, Dalton Trans., 2011, 40, 8072 DOI: 10.1039/C1DT10859J

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