Issue 8, 2012
From the journal:

Chemical Communications

A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane†

Senem Karahan,‡a   Mehmet Zahmakıran§*a  and  Saim Özkara  

* Corresponding authors

a Department of Chemistry, Middle East Technical University, Ankara, Turkey

Abstract

A new type of supported rhodium nanoparticles were reproducibly prepared from N2H4BH3 reduction of [Rh(μ-Cl)(1,5-cod)]2 without using any solid support and pre-treatment technique. Their characterization shows the formation of well dispersed rhodium(0) nanoparticles within the framework of a polyaminoborane based polymeric support. These new rhodium(0) nanoparticles were found to be the most active supported catalyst in the catalytic dehydrogenation of ammonia-borane in water at room temperature.

Graphical abstract: A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane

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Article information

DOI
https://doi.org/10.1039/C1CC15864C
Article type
Communication
Submitted
21 Sep 2011
Accepted
17 Nov 2011
First published
08 Dec 2011

Chem. Commun., 2012,48, 1180-1182

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A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane

S. Karahan, M. Zahmakıran and S. Özkar, Chem. Commun., 2012, 48, 1180 DOI: 10.1039/C1CC15864C

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