Issue 44, 2011
From the journal:

Chemical Communications

Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(ii) complex†‡

W. Jeffrey McCarty,a   Xiaoping Yanga  and  Richard A. Jones*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas, USA
E-mail: rajones@mail.utexas.edu
Tel: + 1 (512) 471-1706

Abstract

Reaction of 3,5-(CF3)2PzLi with anhydrous RhCl3 in THF gives [Li(THF)]2Rh(μ-3,5-(CF3)2Pz)4 (1) as a rare example of a mononuclear, paramagnetic Rh(II) complex (Pz = pyrazolate).

Graphical abstract: Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(ii) complex

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Article information

DOI
https://doi.org/10.1039/C1CC15428A
Article type
Communication
Submitted
01 Sep 2011
Accepted
26 Sep 2011
First published
11 Oct 2011

Chem. Commun., 2011,47, 12164-12166

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Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(II) complex

W. J. McCarty, X. Yang and R. A. Jones, Chem. Commun., 2011, 47, 12164 DOI: 10.1039/C1CC15428A

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