Issue 34, 2011
From the journal:

Chemical Communications

An isolable, metastable, geometrically unique manganese(iv) trihydrazide complex poised for reactivity†

Shivaiah Vaddypally,a   Sandeep K. Kondaveetia  and  Michael J. Zdilla*a  

* Corresponding authors

a Department of Chemistry, Temple University, 1901 N. 13th Street, Philadelphia, USA
E-mail: mzdilla@temple.edu
Fax: +1 (215) 204-1532
Tel: +1 (215) 204-7886

Abstract

A metastable Mn(IV) tris(N,N′)diphenylhydrazide complex, Li2Mn(κ2-N2Ph2)3 (1) has been prepared, and characterized by X-ray diffraction analysis and spectroscopic techniques. Mn precursors are reacted with LiNHtBu to form an intermediate manganese-imido mixture, which reacts with N,N′-diphenylhydrazine, oxidizing the metal, and forming 1. Despite ease of formation, 1 is poised for reactivity, as loss of ether ligand triggers reductive elimination of azobenzene.

Graphical abstract: An isolable, metastable, geometrically unique manganese(iv) trihydrazide complex poised for reactivity

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Article information

DOI
https://doi.org/10.1039/C1CC13427B
Article type
Communication
Submitted
09 Jun 2011
Accepted
08 Jul 2011
First published
29 Jul 2011

Chem. Commun., 2011,47, 9696-9698

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An isolable, metastable, geometrically unique manganese(IV) trihydrazide complex poised for reactivity

S. Vaddypally, S. K. Kondaveeti and M. J. Zdilla, Chem. Commun., 2011, 47, 9696 DOI: 10.1039/C1CC13427B

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