Issue 5, 2011

Polymerization of substituted acetylenes and features of the formed polymers

Abstract

Progress in the polymerization of substituted acetylenes and the properties and functions of the formed polymers that have been synthesized in the past several years are surveyed. Polymerizationcatalysts for substituted acetylenes, new monomers and polymers, controlled polymerizations, and photoelectronic functions and separation membranes of substituted polyacetylenes are discussed. A focus is placed on the development of novel rhodiumcatalysts for the polymerization of phenylacetylenes, the helical structures of the polymers obtained from chiral monosubstituted acetylenes, and highly gas-permeable polymers prepared from disubstituted acetylenes, in which great advances have been made recently.

Graphical abstract: Polymerization of substituted acetylenes and features of the formed polymers

Article information

Article type
Review Article
Submitted
05 Oct 2010
Accepted
17 Nov 2010
First published
22 Dec 2010

Polym. Chem., 2011,2, 1044-1058

Polymerization of substituted acetylenes and features of the formed polymers

M. Shiotsuki, F. Sanda and T. Masuda, Polym. Chem., 2011, 2, 1044 DOI: 10.1039/C0PY00333F

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