Issue 40, 2010
From the journal:

Chemical Communications

Isoquinoline-based chiral monodentate N-heterocyclic carbenes†

Dimitri Hirsch-Weil,a   Khalil A. Abbouda  and  Sukwon Hong*a  

* Corresponding authors

a Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, USA
E-mail: sukwon@ufl.edu
Fax: +1-352-846-0296
Tel: +1-352-392-6787

Abstract

C 1-symmetric isoquinoline-based chiral diaminocarbene ligands (MIQ) have been developed to block three quadrants of the metal coordination sphere, complementing C2-symmetric biisoquinoline-based ligands (BIQ). MIQ-Cu complexes catalyzed conjugate borylation of various α,β-unsaturated amides in good yields (82–99%) and enantioselectivities (75–87% ee).

Graphical abstract: Isoquinoline-based chiral monodentate N-heterocyclic carbenes

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Article information

DOI
https://doi.org/10.1039/C0CC02211J
Article type
Communication
Submitted
29 Jun 2010
Accepted
18 Aug 2010
First published
13 Sep 2010

Chem. Commun., 2010,46, 7525-7527

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Isoquinoline-based chiral monodentate N-heterocyclic carbenes

D. Hirsch-Weil, K. A. Abboud and S. Hong, Chem. Commun., 2010, 46, 7525 DOI: 10.1039/C0CC02211J

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