Issue 10, 2010
From the journal:

Dalton Transactions

The first anionic four-connected boron imidazolate framework†

Jian Zhang,a   Shumei Chena  and  Xianhui Bu*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840
E-mail: xbu@csulb.edu

Abstract

Reported here is an organic-cation templated 4-connected anionic boron imidazolate framework [N(CH3)4][Cd(SH)2B(im)4] (ABIF-1, im = imidazolyl), which is synthesized from the reaction of the supertetrahedral Cd10S4(SPh)12 cluster with [N(CH3)4]Cl and NaB(im)4. The work represents an important step in the expansion of boron imidazolate frameworks from neutral BIFs to anionic ABIFs.

Graphical abstract: The first anionic four-connected boron imidazolate framework

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Article information

DOI
https://doi.org/10.1039/B925714D
Article type
Communication
Submitted
07 Dec 2009
Accepted
14 Jan 2010
First published
21 Jan 2010

Dalton Trans., 2010,39, 2487-2489

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The first anionic four-connected boron imidazolate framework

J. Zhang, S. Chen and X. Bu, Dalton Trans., 2010, 39, 2487 DOI: 10.1039/B925714D

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