Issue 44, 2009
From the journal:

Chemical Communications

Active species of CeAl4 in the CeCl3-doped sodium aluminium hydride and its enhancement on reversible hydrogen storage performance

Xiulin Fan,a   Xuezhang Xiao,a   Lixin Chen,*a   Kairong Yu,a   Zhe Wu,a   Shouquan Lia  and  Qidong Wanga  

* Corresponding authors

a Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P.R. China
E-mail: lxchen@zju.edu.cn
Fax: +86 571 8795 1152
Tel: +86 571 8795 1152

Abstract

By directly doping CeAl4 into sodium aluminium hydride, which probably serves as the active species in the hydriding and dehydriding processes of CeCl3-doped NaAlH4, a high reversible hydrogen capacity of 4.77–4.92 wt% (close to expected capacity of 5.13 wt%) can be achieved in less than 20 min under moderate conditions.

Graphical abstract: Active species of CeAl4 in the CeCl3-doped sodium aluminium hydride and its enhancement on reversible hydrogen storage performance

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Article information

DOI
https://doi.org/10.1039/B916898B
Article type
Communication
Submitted
17 Aug 2009
Accepted
17 Sep 2009
First published
05 Oct 2009

Chem. Commun., 2009, 6857-6859

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Active species of CeAl4 in the CeCl3-doped sodium aluminium hydride and its enhancement on reversible hydrogen storage performance

X. Fan, X. Xiao, L. Chen, K. Yu, Z. Wu, S. Li and Q. Wang, Chem. Commun., 2009, 6857 DOI: 10.1039/B916898B

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