Issue 41, 2009
From the journal:

Dalton Transactions

On the mechanism of isospecific epoxidepolymerization by salen cobalt(III) complexes: Evidence for solid-state catalysis†

Hiroharu Ajiro,a   Kathryn L. Peretti,a   Emil B. Lobkovskya  and  Geoffrey W. Coates*a  

* Corresponding authors

a Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York, USA
E-mail: gc39@cornell.edu
Fax: 01 607 255 4137
Tel: 01 607 255 5447

Abstract

Mechanistic studies have revealed that the isospecific polymerization of epoxides by a discrete salen cobalt(III) catalyst occurs at the surface of the undissolved, crystalline complex.

Graphical abstract: On the mechanism of isospecific epoxide polymerization by salen cobalt(III) complexes: Evidence for solid-state catalysis

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Article information

DOI
https://doi.org/10.1039/B914573G
Article type
Communication
Submitted
20 Jul 2009
Accepted
14 Sep 2009
First published
30 Sep 2009

Dalton Trans., 2009, 8828-8830

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On the mechanism of isospecific epoxide polymerization by salen cobalt(III) complexes: Evidence for solid-state catalysis

H. Ajiro, K. L. Peretti, E. B. Lobkovsky and G. W. Coates, Dalton Trans., 2009, 8828 DOI: 10.1039/B914573G

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