Issue 32, 2009
From the journal:

Dalton Transactions

First hexanuclear zirconiummacrocycle sustained in a chair-like conformation by glycolic acids†

Michael Fitzgerald,a   Iraklis Pappas,a   Chong Zheng,b   Zai-Lai Xie,c   Xiao-Ying Huang,c   Songtao Taod  and  Long Pan*a  

* Corresponding authors

a Colgate-Palmolive Company, 909 River Road, Piscataway, NJ, USA
E-mail: long_pan@colpal.com

b Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois, USA

c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China

d College of Physics and Electronic Information, Anhui Normal University, Wuhu, China

Abstract

A discrete, hexanuclear zirconium metallocycle has been synthesized, isolated, and characterized by single-crystal X-ray diffraction. It is sustained in a chair-like conformation by glycolic acids. Formation and growth of the complex has been observed using in situ time-resolved dynamic light scattering measurements.

Graphical abstract: First hexanuclear zirconium macrocycle sustained in a chair-like conformation by glycolic acids

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Article information

DOI
https://doi.org/10.1039/B912160A
Article type
Communication
Submitted
19 Jun 2009
Accepted
26 Jun 2009
First published
15 Jul 2009

Dalton Trans., 2009, 6289-6291

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First hexanuclear zirconium macrocycle sustained in a chair-like conformation by glycolic acids

M. Fitzgerald, I. Pappas, C. Zheng, Z. Xie, X. Huang, S. Tao and L. Pan, Dalton Trans., 2009, 6289 DOI: 10.1039/B912160A

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