Issue 13, 2009

Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

Abstract

Air-stable Lewis acidic μ2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.

Graphical abstract: Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

Supplementary files

Article information

Article type
Communication
Submitted
28 Nov 2008
Accepted
19 Jan 2009
First published
12 Feb 2009

Chem. Commun., 2009, 1679-1681

Synthesis and structure of air-stable Lewis acidic binuclear complex of zirconocene pentafluorophenylsulfonate and its catalytic application in the allylation of carbonyl compounds with tetraallyltin

R. Qiu, X. Xu, Y. Li, G. Zhang, L. Shao, D. An and S. Yin, Chem. Commun., 2009, 1679 DOI: 10.1039/B821366F

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