Issue 18, 2009
From the journal:

Chemical Communications

In situ generation of novel acyclic diaminocarbene–copper complex†

Dimitri Hirsch-Weil,a   David R. Snead,a   Sebastien Inagaki,a   Hwimin Seo,a   Khalil A. Abbouda  and  Sukwon Hong*a  

* Corresponding authors

a Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, USA
E-mail: sukwon@ufl.edu
Fax: +1-352- 846-0296
Tel: +1-352-392-6787

Abstract

A novel acyclic diaminocarbene–copper complex appears to be generated from a chloroamidinium salt and Cu(I)-thiophenecarboxylate in the presence of Grignard reagent based on 13C NMR studies and is a highly efficient catalyst for SN2′-allylic alkylation.

Graphical abstract: In situ generation of novel acyclic diaminocarbene–copper complex

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Article information

DOI
https://doi.org/10.1039/B821169H
Article type
Communication
Submitted
27 Nov 2008
Accepted
10 Mar 2009
First published
03 Apr 2009

Chem. Commun., 2009, 2475-2477

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In situ generation of novel acyclic diaminocarbene–copper complex

D. Hirsch-Weil, D. R. Snead, S. Inagaki, H. Seo, K. A. Abboud and S. Hong, Chem. Commun., 2009, 2475 DOI: 10.1039/B821169H

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