Synthesis and properties of the anti and syn isomers of dibenzothieno[b,d]pyrrole

Ting Qi; Yunlong Guo; Yunqi Liu; Hongxia Xi; Hengjun Zhang; Xike Gao; Ying Liu; Kun Lu; Chunyan Du; Giu Yu; Daoben Zhu

doi:10.1039/B813683A

Synthesis and properties of the anti and syn isomers of dibenzothieno[b,d]pyrrole†‡§

Ting Qi,^ab Yunlong Guo,^ab Yunqi Liu,*^a Hongxia Xi,^ab Hengjun Zhang,^ab Xike Gao,^ab Ying Liu,^ab Kun Lu,^ab Chunyan Du,^ab Giu Yu^a and Daoben Zhu^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: liuyq@iccas.ac.cn

^b Graduate School of Chinese Academy of Sciences, Beijing, China

Abstract

A novel type of anti and syn isomers of a pentacyclic compound consisting of two thiophene rings and one pyrrole ring were efficiently synthesized from benzo[b]thiophene, and the anti isomer exhibits better charge transport and OFET properties compared with the syn isomer and its N-hexyl substitution.

Chemical Communications

Synthesis and properties of the anti and syn isomers of dibenzothieno[b,d]pyrrole†‡§

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Synthesis and properties of the anti and syn isomers of dibenzothieno[b,d]pyrrole

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