Issue 9, 2008

Intramolecularcation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

Abstract

NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular π-stacking.

Graphical abstract: Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

Supplementary files

Article information

Article type
Communication
Submitted
01 Nov 2007
Accepted
06 Dec 2007
First published
08 Jan 2008

Chem. Commun., 2008, 1082-1084

Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

I. Richter, J. Minari, P. Axe, J. P. Lowe, T. D. James, K. Sakurai, S. D. Bull and J. S. Fossey, Chem. Commun., 2008, 1082 DOI: 10.1039/B716937J

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