Issue 13, 2007
From the journal:

Chemical Communications

Reversibility in the boron-mediated ketone–ketone aldol reaction†

Katie M. Cergol,a   Paul Jensen,a   Peter Turnera  and  Mark J. Coster*a  

* Corresponding authors

a School of Chemistry (F11), The University of Sydney, Australia
E-mail: m.coster@chem.usyd.edu.au
Fax: +61 2 9351 3329
Tel: +61 2 9351 2752

Abstract

The boron-mediated ketone–ketone aldol reaction is demonstrated, through 1H NMR studies, to be reversible, in contrast to the strictly irreversible aldol reactions of boron enolates with aldehydes.

Graphical abstract: Reversibility in the boron-mediated ketone–ketone aldol reaction

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Article information

DOI
https://doi.org/10.1039/B617094C
Article type
Communication
Submitted
22 Nov 2006
Accepted
10 Jan 2007
First published
22 Jan 2007

Chem. Commun., 2007, 1363-1365

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Reversibility in the boron-mediated ketone–ketone aldol reaction

K. M. Cergol, P. Jensen, P. Turner and M. J. Coster, Chem. Commun., 2007, 1363 DOI: 10.1039/B617094C

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