Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon® membranes embedding a fluorous-tagged decatungstate

Mauro Carraro; Martino Gardan; Gianfranco Scorrano; Enrico Drioli; Enrica Fontananova; Marcella Bonchio

doi:10.1039/B610551C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon^® membranes embedding a fluorous-tagged decatungstate†

Mauro Carraro,^a Martino Gardan,^a Gianfranco Scorrano,^a Enrico Drioli,^b Enrica Fontananova^b and Marcella Bonchio*^a

Author affiliations

* Corresponding authors

^a ITM-CNR and Department of Chemical Sciences, University of Padova, Via Marzolo, 1, Padova, Italy

^b ITM-CNR at University of Calabria, Via P. Bucci, Cubo 17C, Rende (CS), Italy

Abstract

Hybrid fluoropolymeric membranes with 25% loading of the fluorous-tagged (R_fN)₄W₁₀O₃₂ effect the solvent-free photooxygenation of benzylic C–H bonds with up to 6100 TONs in 4 hours.

Download options Please wait...

Supplementary files

Experimental section, catalyst and membrane characterization, oxygenation kinetics PDF (2586K)

Article information

DOI: https://doi.org/10.1039/B610551C
Article type: Communication
Submitted: 24 Jul 2006
Accepted: 29 Aug 2006
First published: 18 Sep 2006

Download Citation

Chem. Commun., 2006, 4533-4535

Permissions

Request permissions

Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon^® membranes embedding a fluorous-tagged decatungstate

M. Carraro, M. Gardan, G. Scorrano, E. Drioli, E. Fontananova and M. Bonchio, Chem. Commun., 2006, 4533 DOI: 10.1039/B610551C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications