Issue 29, 2006

New S/O-substituted ferrocenediyl ligands and their metal complexes

Abstract

New unsymmetrical S/O 1,1′-disubstituted ferrocenediyl ethers and hydroxides have been synthesised. The coordination chemistry of 1-(methylsulfanyl)-1′-(methoxy)ferrocene 6 has been investigated with palladium(II) and platinum(II) precursors. With palladium(II), a bis-µ-chloro-bridged dimeric complex 10 was obtained with the ligand bound solely through the thioether donor group. With platinum(II), a bis-ligand trans-sulfur ligated complex 11 was obtained and structurally characterised.

Graphical abstract: New S/O-substituted ferrocenediyl ligands and their metal complexes

Supplementary files

Article information

Article type
Paper
Submitted
20 Feb 2006
Accepted
11 Apr 2006
First published
28 Apr 2006

Dalton Trans., 2006, 3597-3602

New S/O-substituted ferrocenediyl ligands and their metal complexes

R. C. J. Atkinson, V. C. Gibson, N. J. Long, L. J. West and A. J. P. White, Dalton Trans., 2006, 3597 DOI: 10.1039/B602576E

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