Issue 19, 2006
From the journal:

Chemical Communications

Oxidative N-dealkylation in cobalt–bispidine–H2O2 systems†

Peter Comba,*a   Shigemasa Kuwata,a   Gerald Linti,a   Hans Pritzkow,a   Máté Tarnaia  and  Hubert Wadepohla  

* Corresponding authors

a Universität Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, Heidelberg, Germany
E-mail: peter.comba@aci.uni-heidelberg.de
Fax: +49-6221-546617

Abstract

The reaction of the CoII complex with the rigid bispidine ligand L1 with two tertiary amine and two pyridine donors, [CoII(L1)(OH2)2]2+, with H2O2 and O2 produces [CoII(L2)(OH2)2]3+, where L2 is demethylated at one of the amine donors, and CH2O.

Graphical abstract: Oxidative N-dealkylation in cobalt–bispidine–H2O2 systems

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Article information

DOI
https://doi.org/10.1039/B602571D
Article type
Communication
Submitted
21 Feb 2006
Accepted
27 Mar 2006
First published
11 Apr 2006

Chem. Commun., 2006, 2074-2076

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Oxidative N-dealkylation in cobalt–bispidine–H2O2 systems

P. Comba, S. Kuwata, G. Linti, H. Pritzkow, M. Tarnai and H. Wadepohl, Chem. Commun., 2006, 2074 DOI: 10.1039/B602571D

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