Issue 27, 2005
From the journal:

Chemical Communications

Mono- and digallane complexes of a tridentate amido-diamine ligand†

Bing Luo,a   Benjamin E. Kuceraa  and  Wayne L. Gladfelter*a  

* Corresponding authors

a Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis
E-mail: gladfelt@chem.umn.edu
Fax: +1 612-626-0859
Tel: +1 612-624-4391

Abstract

Bis(2-dimethylaminoethyl)amido gallane, H2GaN(CH2CH2NMe2)2, that melts at 27 °C and remains stable upon heating at 55 °C for two days, was synthesized either from the reaction of the quinuclidine adduct of monochlorogallane with the lithium salt of the corresponding amine, or from the reaction of trimethylamine gallane and the amine; the latter affords an unusual co-product with both GaH2 and GaH3 bonded to the same amido nitrogen.

Graphical abstract: Mono- and digallane complexes of a tridentate amido-diamine ligand

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Article information

DOI
https://doi.org/10.1039/B503705K
Article type
Communication
Submitted
11 Mar 2005
Accepted
16 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3463-3465

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Mono- and digallane complexes of a tridentate amido-diamine ligand

B. Luo, B. E. Kucera and W. L. Gladfelter, Chem. Commun., 2005, 3463 DOI: 10.1039/B503705K

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