Issue 15, 2004
From the journal:

Chemical Communications

Preparation and structural characterisation of methoxybis(trimethylsilyl)silyl potassium and its condensation product

Pravin R. Likhar,a   Michaela Zirngast,a   Judith Baumgartnera  and  Christoph Marschner*a  

* Corresponding authors

a Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010 Graz, Austria
E-mail: marschner@anorg.tu-graz.ac.at
Fax: +43 316 873 8701
Tel: +43 316 873 8209

Abstract

Depending on the conditions the reaction of tris(trimethylsilyl)methoxysilane (1) with potassium tert-butoxide either in benzene and in the presence of 18-crown-6 or in THF gives either the crown ether adduct of potassium-methoxybis(trimethylsilyl)silane (2), or 2-methoxytetrakis(trimethylsilyl)disilanyl potassium (3).

Graphical abstract: Preparation and structural characterisation of methoxybis(trimethylsilyl)silyl potassium and its condensation product

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B406074A
Article type
Communication
Submitted
23 Apr 2004
Accepted
27 May 2004
First published
28 Jun 2004

Chem. Commun., 2004, 1764-1765

Permissions

Request permissions

Preparation and structural characterisation of methoxybis(trimethylsilyl)silyl potassium and its condensation product

P. R. Likhar, M. Zirngast, J. Baumgartner and C. Marschner, Chem. Commun., 2004, 1764 DOI: 10.1039/B406074A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements