Issue 97, 2002

Interlocking molecular grid lattices involving weak assembly forces

Abstract

The X-ray structures of the two diquinoline derivatives 6,13-dihydro-6,13-ethano-5,12-diazapentacene (1) and 6α,13α-dibromo-2,9-dichloro-5bα,6,12bα,13-tetrahydropentaleno[1,2-b:4,5-b′]diquinoline (2) reveal that both crystallise by forming network lattices involving only weak intermolecular forces. These very similar lattices contain no aryl edge–edge C–H⋯N R22(8) dimers or efficient aryl offset face–face interactions, commonly found in related diquinoline crystals. Both lattices arise from multiple interlocking, at an inclined angle, of two identical sets of parallel molecular grids. Each grid connector site comprises a centrosymmetric tetramer of molecules held together by weak intermolecular forces, unlike the metal co-ordination motifs normally used to generate grid structures. Edge–edge C–H⋯N weak hydrogen bonds of various types help stabilise these structures by linking molecules of opposite handedness in neighbouring grids.

Supplementary files

Article information

Article type
Paper
Submitted
10 Oct 2002
Accepted
01 Nov 2002
First published
11 Nov 2002

CrystEngComm, 2002,4, 585-590

Interlocking molecular grid lattices involving weak assembly forces

S. F. Alshahateet, A. N. M. M. Rahman, R. Bishop, D. C. Craig and M. L. Scudder, CrystEngComm, 2002, 4, 585 DOI: 10.1039/B209897K

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