Issue 11, 2001
From the journal:

New Journal of Chemistry

Four two-dimensional highly undulating silver(I)–hexamethylenetetramine co-ordination networks containing micropores

Shao-Liang Zheng,a   Ming-Liang Tong,*a   Hai-Liang Zhua  and  Xiao-Ming Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Zhongshan Uniersity, Guangzhou, China
E-mail: cescxm@zsu.edu.cn; cestml@zsu.edu.cn

Abstract

Four interesting polymers, namely [Ag2(μ3-hmt)2(MeCN)](ClO4)21, [Ag(μ3-hmt)(ma)] 2, [Ag(μ3-hmt)(ba)]·H2O 3 and [Ag(μ3-hmt)(sal)]·H2O 4 (hmt = hexamethylenetetramine, ma = malonate, ba = benzoate and sal = salicylate) have been synthesised and structurally characterised by X-ray diffraction. In these complexes, the two-dimensional [Ag(μ3-hmt)] layers of hexagonal units are highly undulating and each pair of adjacent lateral ligands, MeCN or carboxylates, at the same side of the layers are slanted towards each other, resulting in intralayer micropores.

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Article information

DOI
https://doi.org/10.1039/B107193A
Article type
Paper
Submitted
08 Aug 2001
Accepted
14 Sep 2001
First published
19 Oct 2001

New J. Chem., 2001,25, 1425-1429

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Four two-dimensional highly undulating silver(I)–hexamethylenetetramine co-ordination networks containing micropores

S. Zheng, M. Tong, H. Zhu and X. Chen, New J. Chem., 2001, 25, 1425 DOI: 10.1039/B107193A

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