Issue 15, 2000

Unique chains of alternating octahedral and tetrahedral cobalt(ii) sites: crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH) 2]n and [{Co4(μ-Cl)6Cl2(thf)4( H2O)2}·2THF]n Electronic supplementary information (ESI) available: elemental analysis, FTIR, VIS–NIR, temperature dependence of magnetic moment, data and apparatus for 1. See http://www.rsc.org/suppdata/cc/b0/b003213l/

Abstract

[Co4(μ-Cl)6Cl2(thf)4 (MeOH)2]n, a catena-polycobalt(II) complex with an unusual linear chain of octahedral/tetrahedral/octahedral cobalt sites, is obtained quantitatively from the reaction between cobalt chloride hydrate and trimethylorthoformate in THF.

Supplementary files

Article information

Article type
Communication
Submitted
20 Apr 2000
Accepted
07 Jun 2000
First published
04 Jul 2000

Chem. Commun., 2000, 1359-1360

Unique chains of alternating octahedral and tetrahedral cobalt(II) sites: crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH) 2]n and [{Co4(μ-Cl)6Cl2(thf)4( H2O)2}·2THF]n

J. Hierso, D. D. Ellis, A. L. Spek, E. Bouwman and J. Reedijk, Chem. Commun., 2000, 1359 DOI: 10.1039/B003213L

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements