Issue 13, 2000

Synthesis and structures of one-dimensional co-ordination polymers derived from bismuth(III) selenoether macrocyclic complexes

Abstract

Treatment of BiX3 (X = Cl or Br) with [8]aneSe2 (1,5-diselenacyclooctane), [16]aneSe4 (1,5,9,13-tetraselenacyclohexadecane), [24]aneSe6 (1,5,9,13,17,21-hexaselenacyclotetracosane) yielded species of formula [BiX3(L)] in moderate to high yield as intensely coloured powdered solids. The crystal structures of [BiCl3([8]aneSe2)] and [BiBr3([16]aneSe4)] each reveal infinite one-dimensional ladder structures derived from almost planar Bi2X6 dimer units linked by μ-bridging cyclic selenoethers. Each Bi is co-ordinated to a Se2X4 donor set, with the Se donor atoms occupying mutually trans co-ordination sites. The selenoether ligands adopt exocyclic arrangements and, in [BiBr3([16]aneSe4)], it is two trans Se atoms which co-ordinate to BiIII, leaving the other two Se atoms non-co-ordinating. The structures of these species are contrasted with related complexes involving acyclic selenoether ligands and with the few structurally characterised bismuth(III) halide complexes with macrocyclic thioether ligands.

Supplementary files

Article information

Article type
Paper
Submitted
22 Mar 2000
Accepted
09 May 2000
First published
12 Jun 2000

J. Chem. Soc., Dalton Trans., 2000, 2163-2166

Synthesis and structures of one-dimensional co-ordination polymers derived from bismuth(III) selenoether macrocyclic complexes

A. J. Barton, A. R. J. Genge, W. Levason and G. Reid, J. Chem. Soc., Dalton Trans., 2000, 2163 DOI: 10.1039/B002287J

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