Spectroscopic and crystallographic studies shows that the epoxidation, osmylation and bromination of 17β-acetoxy-5β-androst-3-ene takes place from the β-face of the alkene and that a diequatorial dibromide and bromohydrin accompany the diaxial addition products.
J. R. Hanson, P. B. Hitchcock, S. N. Al-Jayyousi and C. Uyanik, J. Chem. Res. (S), 1998, 420 DOI: 10.1039/A800578H
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