Issue 17, 1998
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

A new synthesis of π-electron conjugated phosphonates and phosphonic bis(diethylamides) and their SHG activities

Takuji Ogawa,   Naoya Usuki  and  Noboru Ono  

Abstract

A series of vinylic and arylic phosphonates and phosphonic bis(diethylamides) were prepared by copper promoted substitution of the corresponding bromides. These π-electron conjugated phosphonates and phosphonic bis(diethylamides) were investigated to elucidate their optical and second harmonic generation (SHG) properties; it was found that diphenyl 2-(4-dimethylaminophenyl)ethenylphosphonate exhibited strong SHG activity, the efficiency being 13 times greater than that of urea.

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Article information

DOI
https://doi.org/10.1039/A709082J
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1998, 2953-2958

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A new synthesis of π-electron conjugated phosphonates and phosphonic bis(diethylamides) and their SHG activities

T. Ogawa, N. Usuki and N. Ono, J. Chem. Soc., Perkin Trans. 1, 1998, 2953 DOI: 10.1039/A709082J

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