Volume 65, 1969
From the journal:

Transactions of the Faraday Society

Perturbation approach to the free energy of solution

G. R. Luckhurst  and  D. E. Martire  

Abstract

A perturbation treatment, based on a statistical approach due to Longuet-Higgins, is developed for the free energy of solution. By assuming that the different free energies of solution within a set of closely-related molecules arise solely from the different strengths of interactions of the molecules with the solvent, the thermal contribution to the activity coefficient of a solute, 2 should be related to that of a reference solute, 2′, by [graphic omitted] The results for four sets of alkane isomers in seven solvents confirm the validity of this equation.

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Article information

DOI
https://doi.org/10.1039/TF9696501248
Article type
Paper

Trans. Faraday Soc., 1969,65, 1248-1254

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Perturbation approach to the free energy of solution

G. R. Luckhurst and D. E. Martire, Trans. Faraday Soc., 1969, 65, 1248 DOI: 10.1039/TF9696501248

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