Issue 1, 1993
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4. 1,3-Migration of the phenyl group

Colin Eaborn,   Paul D. Lickiss,   Sabah T. Najim  and  Włodzimierz A. Stańczyk  

Abstract

The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C (SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C (SiEt2Ph)(SiMe2F). The reaction is thought to proceed via a cation, II, in which there is a 1,3-phenyl bridge between silicon atoms. Reaction of the organolithium reagent (Me3Si)2C(SiMe2Ph)Li, R′Li, with Me2SiHCl, Et2SiHCl, Et2SiF2 and Et2SiCl2 gives the products R′SiMe2H, R′SiEt2H, R′SiEt2F and R′SiEt2Cl, respectively.

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Article information

DOI
https://doi.org/10.1039/P29930000059
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1993, 59-62

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Reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4. 1,3-Migration of the phenyl group

C. Eaborn, P. D. Lickiss, S. T. Najim and W. A. Stańczyk, J. Chem. Soc., Perkin Trans. 2, 1993, 59 DOI: 10.1039/P29930000059

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